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Synlett 2000; 2000(2): 221-222
DOI: 10.1055/s-2000-6491
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Towards the Total Synthesis of Octalactin A

Guillaume Bluet* , Jean-Marc Campagne
  • *ICSN-CNRS, Avenue de la Terrasse, 91198 Gif sur Yvette, France; Fax +33 1 69 82 30 73; E-mail: Jean-Marc.Campagne@icsn.cnrs-gif.fr
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Publikationsdatum:
31. Dezember 2000 (online)

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In the course of a total synthesis of octalactin A, the (C1-C7) and (C8-C15) sub-units have been built up using catalytic asymmetric reactions; specifically, an asymmetric Shi epoxidation and a vinylogous Mukaiyama-aldol reaction.

asymmetric catalysis - lactones - natural products - octalactin - vinylogous Mukaiyama