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Synlett 2000; 2000(3): 382-384
DOI: 10.1055/s-2000-6535
DOI: 10.1055/s-2000-6535
letter
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Observations on the Use of Triphenylphosphonium Bromide as a Mild and Quantifiable Source of Hydrogen Bromide for Chemoselective Ring Opening of Epoxides to Bromohydrins
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/200003/lookinside/thumbnails/10.1055-s-2000-6535-1.jpg)
The chemoselective ring opening of epoxides to bromohydrins in the presence of ketal, benzyloxymethoxy and trimethylsilyl ether functionality using triphenylphosphonium bromide is described. The preparation of a polymer supported variant is also reported.
triphenylphosphonium bromide - epoxide ring opening - bromohydrins