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Synlett 2000; 2000(4): 517-519
DOI: 10.1055/s-2000-6588
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Palladium-Catalyzed Allylic Alkylation Using a Novel Chiral Imino-Phosphine Ligand Derived from 1-Mesitylethylamine

Takehiro Kohara* , Yukihiko Hashimoto, Kazuhiko Saigo
  • *Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan
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Publikationsdatum:
31. Dezember 2000 (online)

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A novel chiral imino-phosphine ligand was prepared from enantiopure 1-mesitylethylamine and o-(diphenylphosphino)benzaldehyde. The chiral ligand was found to be effective for a palladium-catalyzed allylic alkylation.

asymmetric allylic alkylation - asymmetric catalyst - palladium - imino-phosphine - 1-mesitylethylamine