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Synlett 2000; 2000(9): 1342-1344
DOI: 10.1055/s-2000-7139
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New Advances in Radical Cascades Based on the Use of Vinyl Radicals

Louis Fensterbank* , Emily Mainetti, Priscille Devin, Max Malacria
  • *Université P. et M. Curie, Laboratoire de Chimie Organique de Synthèse, associé au CNRS, Tour 44-54, B. 229, 4, place Jussieu, 75252 Paris Cedex, France; E-mail: malacria@ccr.jussieu.fr
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Publication Date:
31 December 2000 (online)

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New radical sequences based on vinyl radicals have allowed the synthesis of various polycycles, such as angularly-fused 5-6-5 and 5-8-5 frameworks.

radical reactions - polycycles - cyclizations - hydrogen transfer - stereoselective synthesis