RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000083.xml
Synlett 2001; 2001(7): 1113-1116
DOI: 10.1055/s-2001-15151
DOI: 10.1055/s-2001-15151
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Asymmetric Synthesis of (R)-Limonene and (S)-Cembrene-A by an Intramolecular Cyclization Reaction Using a Chiral Leaving Group
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
31. Dezember 2001 (online)
![](https://www.thieme-connect.de/media/synlett/200107/lookinside/thumbnails/10.1055-s-2001-15151-1.jpg)
A six-membered monocyclic terpene, (R)-limonene, and a 14-membered monocyclic diterpene, (S)-cembrene-A, have been synthesized, respectively, by new enantioselective intramolecular cyclization reactions of neryl ether and (all-E)-geranylgeranyl ether using an (R)-1,1'-binaphthyl-2-benzoxy-2'-oxy auxiliary as a chiral leaving group in the presence of tin(IV) chloride.
limonene - cembrene-A - chiral leaving group - intramolecular cyclization - asymmetric synthesis