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Synlett 2001; 2001(11): 1751-1754
DOI: 10.1055/s-2001-18101
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Mixed Branched-Linear Type One-Pot Glycosylation: Synthesis of Hepta β-D-glucoside

Haruo Yamada* , Hisami Takimoto, Takeji Ikeda, Hirokazu Tsukamoto, Takeo Harada, Takashi Takahashi
  • *Department of Applied Chemistry, Tokyo Institute of Technology, Ookayama, Meguro, Tokyo 152-8552, Japan; Fax + 81(3)57 34 28 84; E-mail: ttakashi@o.cc.titech.ac.jp
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Publikationsdatum:
29. Oktober 2001 (online)

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A mixed branched-linear type one-pot glycosylation (OPG), which formed three glycosidic linkages in a single reaction vessel, has been developed. Synthesis of protected hepta β-D-glucoside has been achieved in three steps from monosaccharide building blocks by the OPG.

oligosaccharide synthesis - one-pot glycosylation (OPG) - mixed branched-linear type OPG - orthogonal anomeric leaving groups - hepta β-D-glucoside