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Synlett 2001; 2001(12): 1986-1988
DOI: 10.1055/s-2001-18743
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A Ring Closing Metathesis Based Approach for the Spiroannulation of Cyclopentanes and Cyclohexanes. Formal Synthesis of (±)-Acorones

A. Srikrishna* , M. Srinivasa Rao, Santosh J. Gharpure, N. Chandrasekhar Babu
  • *Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India; Fax: 91 (80) 3600683; E-mail: ask@orgchem.iisc.ernet.in
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Publikationsdatum:
04. Dezember 2001 (online)

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An efficient ring closing methathesis (RCM) reaction based approach was developed for the spiroannulation of cyclopentanes and cyclohexanes and its utility demonstrated in the formal synthesis of the spirosesquiterpenes acorones.

spiroannulation - spiro compounds - metathesis reaction - Claisen rearrangement - acorones

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