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Synlett 2001; 2001(12): 1977-1979
DOI: 10.1055/s-2001-18747
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A Simple Access to 2-Acyl- and 2,5-Diacyl-Phospholide Ions

Patrick Toullec* , François Mathey
  • *Laboratoire ‘Hétéroéléments et Coordination’, URA CNRS 1499, DCPH, Ecole Polytechnique, 91128 Palaiseau Cedex, France; Fax: + 33(169)333990; E-mail: francois.mathey@polytechnique.fr
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Publication Date:
04 December 2001 (online)

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Depending on the reaction conditions (rate of addition, temperature, stoichiometry), the reaction of acyl chlorides with 3,4-dimethylphospholide ion in THF gives the 2-acyl- and 2,5-diacylphospholides.

acyl chlorides - 3,4-dimethylphospholide - sigmatropic shift