Synthesis of Novel Unsymmetrically Bridgehead-substituted Phenylseleno­bicyclo[1.1.1]pentanes

Abstract

The synthesis of the two novel unsymmetrical phenylseleno-substituted bicyclo[1.1.1]pentane derivatives, 1-phenylseleno-3-acetylbicyclo[1.1.1]pentane (2) and 1-phenylseleno-3-diethoxyphosphono bicyclo[1.1.1]pentane (3), by radical addition of organoselenium reagents to [1.1.1]propellane is described.

Key words

bridgehead-substituted bicyclco[1.1.1]pentanes - radical reactions - addition reactions - organoselenium derivatives

References

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