Abstract
Chiral α-(O -carbamoyl)alkyl- and α-(N -carbamoyl)alkylcopper(I) reagents derived from (-)-sparteine-mediated asymmetric lithiation of hindered carbamates react with cationic η3 -allylmolybdenum complexes with retention of configuration.
Key words
(-)-sparteine - nucleophilic addition - η3 -allylmolybdenum complexes - asymmetric deprotonation - carbamates - α-(O -carbamoyl)alkylcopper(I) - α-(N -carbamoyl)alkylcopper(I)
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