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Synlett 2006(4): 0659-0660
DOI: 10.1055/s-2006-932493
DOI: 10.1055/s-2006-932493
SPOTLIGHT
© Georg Thieme Verlag Stuttgart · New York
(Diacetoxy)iodobenzene
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Publikationsverlauf
Publikationsdatum:
20. Februar 2006 (online)
Introduction
(Diacetoxy)iodobenzene (DIB), one of the most signif- icant species among the family of hypervalent iodines, has been widely used as an effective oxidant in synthesis of various compounds, especially those containing heteroatoms like N and O. According to the mechanism, the oxidation can be generally classified as either ionic-type or radical-type. In the latter, the oxidations are usually carried out in the presence of molecular iodine. Both can be utilized to prepare compounds through oxidative ring-opening or cyclic closure. DIB can also be applied to other types of reaction, such as electrophilic addition and bromination.
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