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Synlett 2006(11): 1663-1666
DOI: 10.1055/s-2006-944216
DOI: 10.1055/s-2006-944216
LETTER
© Georg Thieme Verlag Stuttgart · New York
Microwave-Promoted Hydroxycarbonylation in Water Using Gaseous Carbon Monoxide and Pre-Pressurized Reaction Vessels
Weitere Informationen
Received
23 March 2006
Publikationsdatum:
04. Juli 2006 (online)
Publikationsverlauf
Publikationsdatum:
04. Juli 2006 (online)
Abstract
The microwave-promoted hydroxycarbonylation of aryl iodides using reaction vessels pre-pressurized with CO is reported. Reactions are performed using simple palladium salts with loadings of either 0.01 mol% or 1 mol%.
Key words
palladium - carbonylations - catalysis - water - microwave
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References and Notes
Specially designed reactors have been used for gas phase catalysis under microwave irradiation. See ref. 7 and references therein.
8Synthos 3000 available from Anton Paar GmbH (www.anton-paar.com).