Synlett 2007(13): 2025-2028  
DOI: 10.1055/s-2007-984872
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© Georg Thieme Verlag Stuttgart · New York

A Catalytic Synthesis of Aziridines without the Usual Byproducts

Arindam Mazumdar, Zheng Xue, Michael F. Mayer*
Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX 79409-1061, USA
Fax: +1(806)7421289; e-Mail: mf.mayer@ttu.edu;
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Received 9 March 2007
Publikationsdatum:
27. Juni 2007 (online)

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Abstract

Complementary to existing routes, the Lewis acid catalyzed reactions of phenyldiazomethane with α-imino esters selectively produce cis-aziridine-2-carboxylates without competitive formation of enamino ester or carbene dimer byproducts.

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