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Synthesis 2022; 54(03): 754-762
DOI: 10.1055/a-1654-2211
DOI: 10.1055/a-1654-2211
paper
Trimethylsilyl Esters as Novel Dual-Purpose Protecting Reagents
The authors thank the Ministry of Science and Technology in Taiwan (MOST 106-2113-M-005-007 and 107-2113-M-005-021 for S.-Y. Luo), National Chung Hsing University, and Chia Nan University of Pharmacy and Science for financial support.
Abstract
Trimethylsilyl esters, AcOTMS, BzOTMS, TCAOTMS, etc., are inexpensive and chemically stable reagents that pose a negligible environmental hazard. Such compounds prove to serve as efficient dual-purpose reagents to respectively achieve acylation and trimethylsilylation of alcohols under acidic or basic conditions. Herein, a detailed study on protection of various substrates and new methodological investigations is described.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1654-2211.
- Supporting Information
Publication History
Received: 09 August 2021
Accepted after revision: 27 September 2021
Accepted Manuscript online:
27 September 2021
Article published online:
17 November 2021
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