Synthesis 2022; 54(22): 4971-4978
DOI: 10.1055/a-1818-0576
special topic
Aryne Chemistry in Synthesis

3-Trifluoromethylbenzyne: Precise Orientation in Cycloaddition Reaction Enabled Regioselective Synthesis of Trifluoromethylated Triptycenes

Takayuki Iwata
a   Institute for Materials Chemistry and Engineering, Kyushu University, 6-1, Kasugako-en, Kasuga 816-8580, Japan
,
Mizuki Hyodo
b   Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1, Kasugako-en, Kasuga 816-8580, Japan
,
Takumi Fujiwara
b   Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1, Kasugako-en, Kasuga 816-8580, Japan
,
Ryusei Kawano
b   Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1, Kasugako-en, Kasuga 816-8580, Japan
,
Leah Kuhn
c   Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390, USA
,
Igor V. Alabugin
c   Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390, USA
,
a   Institute for Materials Chemistry and Engineering, Kyushu University, 6-1, Kasugako-en, Kasuga 816-8580, Japan
› Author Affiliations
This work was partially supported by the Japan Society for the Promotion of Science (JSPS) KAKENHI (Grant Nos. JP18H02557, JP18H04418, JP18H04624, JP20H04780, JP20K21198, and JP20K15283), Nagase Science Technology Foundation (M.S.), Asahi Glass Foundation (T.I.), and the Integrated Research Consortium on Chemical Sciences (IRCCS) Fusion Emergent Research Program (T.I.). This work was performed under the Cooperative Research Program ‘Network Joint Research Center for Materials and Devices’. L.K. acknowledges support by the National Science Foundation (Graduate Research Fellowship Grant No. 1449440).


Abstract

The first regioselective addition reactions to 3-trifluoromethylbenzyne are reported. Triple cycloaddition of ynolates to the benzyne provided 1,8,13-tris(trifluoromethyl)triptycenes with high regioselectivity. 1-Trifluoromethyltriptycenes were regioselectively obtained by the Diels–Alder reaction of anthranoxides with the benzyne. These selectivities are attributed to the electron-acceptor nature of the trifluoromethyl group on the benzyne.

Supporting Information



Publication History

Received: 14 March 2022

Accepted after revision: 05 April 2022

Accepted Manuscript online:
05 April 2022

Article published online:
31 May 2022

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