The reaction of 2-(alkynyl)benzaldehydes with alcohols in the presence of copper catalyst resulted in the selective synthesis of the 1,2-dihydronaphthalene derivatives. On the reaction, it was proposed that the reaction proceeds via the intramolecular dehydration of alcohols followed by the reaction with 2-(alkynyl)benzaldehydes.
Key words
2-(alkynyl)benzaldehyde - alcohol - 1,2-dihydronaphthalene - dehydration - cyclization - copper catalyst