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Synlett 2023; 34(04): 301-313
DOI: 10.1055/a-1986-7969
DOI: 10.1055/a-1986-7969
synpacts
Special Edition Thieme Chemistry Journals Awardees 2022
Asymmetric Formal [3+2] Cycloaddition Reactions of 3-Isothiocyanato Oxindoles: an Update
This work was supported by the Natural Science Foundation of Hubei Province (No. 2022CFB413), the National Natural Science Foundation of China (Nos. 21602052 and 21702121), the 111 Project (D20015), the start-up funding from Wuhan University (Nos. 691000002 and 600460026) and the TaiKang Center for Life and Medical Sciences, Wuhan University (No. 692000007).
Abstract
3-Isothiocyanato oxindoles are a class of important building blocks which have been widely used in the synthesis of structurally diverse enantioenriched spirooxindoles. In this short review, it is attempted to cover the recent synthetic aspects of 3-isothiocyanato oxindoles participated cascade cyclizations in the last few years (i.e., from 2017 to 2022), with an emphasis on formal [3+2] cycloaddition reactions.
1 Introduction
2 Organocatalyzed Formal [3+2] Cycloaddition of 3-Isothiocyanato Oxindoles
3 Lewis Acid Catalyzed Formal [3+2] Cycloaddition of 3-Isothiocyanato Oxindoles
4 Conclusions
Key words
spirooxindoles - 3-isothiocyanato oxindoles - asymmetric synthesis - organocatalysis - Lewis acid catalysis - cycloaddition reactionPublication History
Received: 16 November 2022
Accepted after revision: 24 November 2022
Accepted Manuscript online:
24 November 2022
Article published online:
21 December 2022
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