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Synthesis 2023; 55(12): 1855-1862
DOI: 10.1055/a-2012-5078
DOI: 10.1055/a-2012-5078
paper
Special Issue dedicated to Prof. Alain Krief
Visible-Light-Mediated Germanylation of Aryl Fluorides: Synthetic and Mechanistic Insights
The Centre National de la Recherche Scientifique (CNRS), the Université Paul Sabatier (UPS), and the Agence Nationale de la Recherche (ANR – 220087, MLC-PhotoPhos) are gratefully acknowledged for financial support of this work.
Dedicated to Prof. Alain Krief on the occasion of his 80th birthday.
Abstract
We describe herein a metal-free synthesis of aryltriphenylgermanes from the reaction of triphenylgermane with fluoro(hetero)arenes in the presence of a base under blue light irradiation. The reaction proceeds under mild conditions and tolerates a few functionalities. The scope and limitations of this unprecedented approach are analyzed based on preliminary mechanistic studies.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2012-5078.
- Supporting Information
- CIF File
Publication History
Received: 28 November 2022
Accepted after revision: 13 January 2023
Accepted Manuscript online:
13 January 2023
Article published online:
13 February 2023
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