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Synthesis 2024; 56(05): 851-859
DOI: 10.1055/a-2226-4152
DOI: 10.1055/a-2226-4152
paper
Nitro Compounds/Alcohols as Oxidant/Reductant Pairs: A Practical Synthesis of Azo Compounds and Ketones
Abstract
Herein, a practical and green method for the synthesis of azobenzenes and ketones is reported using nitro compounds/alcohols as oxidant/reductant pairs under basic conditions. Alcohols and nitro compounds are oxidized/reduced in the absence of any metal catalysts under mild conditions and good yields of the corresponding ketones and azobenzenes are achieved selectively. In addition, the alcohols can even be oxidized with KNO3 or NaNO2.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2226-4152.
- Supporting Information
Publication History
Received: 21 November 2023
Accepted after revision: 11 December 2023
Accepted Manuscript online:
11 December 2023
Article published online:
16 January 2024
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