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Synthesis 2024; 56(24): 3849-3858
DOI: 10.1055/a-2403-2247
DOI: 10.1055/a-2403-2247
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A General Synthesis of 3,7-Di(carboxyalkyl)-Functionalized Pyrimidopteridine Photoredox Catalysts
This project was supported the RoHan Project funded by the German Academic Exchange Service (DAAD, No. 57315854) and the FederalMinistry for Economic Cooperation and Development (BMZ) within the framework ‘SDG Bilateral Graduate School Programmes’. Financial support by the Deutsche Forschungsgemeinschaft (DFG) within theframework of the research training group GRK 2943 SPECTRE (No. 507189291), the priority program SPP 2102 (LO 714/11-2, No. 404479188) and research grant (PO 2055/5-1, No. 519357254) is gratefully acknowledged.
Abstract
In this work, the multi-step synthesis of three novel pyrimidopteridine photoredox catalysts is reported. These catalysts contain di(carboxyalkyl)-substitution at the 3- and 7-positions as handles for further synthetic modifications. The catalysts are fully characterized including by photochemical and electrochemical means. Additionally, a catalytic application in the oxidative annulation of 2-phenylbenzoic acid is presented.
Key words
photoredox catalysis - pyridmidopteridines - organic photoredox catalysts - photophysical characterization - amino acid - heterocyclesSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2403-2247.
- Supporting Information
Publication History
Received: 01 July 2024
Accepted after revision: 26 August 2024
Accepted Manuscript online:
26 August 2024
Article published online:
25 September 2024
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