Diastereoselective Synthesis of
1,2,3-Trisubstituted Indanes via Rhodium(I)-Catalyzed Tandem Conjugate
Additions

Cristina Navarro; Aurelio G. Csákÿ

doi:10.1055/s-0028-1083297

PSP

Diastereoselective Synthesis of 1,2,3-Trisubstituted Indanes via Rhodium(I)-Catalyzed Tandem Conjugate Additions

Cristina Navarro, Aurelio G. Csákÿ*
Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, 28040 Madrid, Spain
Fax: +34(91)3945030; e-Mail: csaky@quim.ucm.es;

Abstract

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Abstract

1,2,3-Trisubstituted indanes are synthesized with high diastereoselectivity in favor of the all-trans products by the reaction of boronic acids with electron-deficient o-divinylbenzenes under rhodium(I) catalysis.

Key words

catalysis - Michael addition - tandem reactions - rhodium - synthesis

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Referenzen

References

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