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Synthesis 2010(2): 259-266
DOI: 10.1055/s-0029-1217103
DOI: 10.1055/s-0029-1217103
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Diethyl [Nitro(diazo)methyl]phosphonate: Synthesis and Reactivity towards Alkenes
Further Information
Received
4 September 2009
Publication Date:
06 November 2009 (online)
Publication History
Publication Date:
06 November 2009 (online)
Abstract
A novel and convenient synthesis of diethyl [nitro(diazo)methyl]phosphonate and its reactions with various alkenes are described. The reactivity of diethyl [nitro(diazo)methyl]phosphonate is shown to be dependent on the structure of the alkene. A number of cyclopropyl α-nitrophosphonates were obtained.
Key words
diazo compounds - phosphonates - alkenes - cyclopropanation - carbenes
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