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Synthesis 2010(11): 1771-1776
DOI: 10.1055/s-0029-1218730
DOI: 10.1055/s-0029-1218730
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Bromodimethylsulfonium Bromide-ZnCl2: A Mild and Efficient Catalytic System for Beckmann Rearrangement
Further Information
Received
23 February 2010
Publication Date:
09 April 2010 (online)
Publication History
Publication Date:
09 April 2010 (online)
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Abstract
Bromodimethylsulfonium bromide, in combination with zinc chloride, has been shown to be an excellent catalytic system for liquid-phase Beckmann rearrangement of various ketoximes into the corresponding amides/lactams in acetonitrile at reflux temperature with good to excellent yields.
Key words
Beckmann rearrangement - ketoximes - amides - bromodimethylsulfonium bromide (BDMS) - catalytic process - Lewis acids
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