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Synthesis 2010(21): 3637-3644
DOI: 10.1055/s-0030-1258237
DOI: 10.1055/s-0030-1258237
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Suzuki-Miyaura Cross-Coupling of 3-Pyridyl Triflates with Alk-1-enyl-2-pinacol Boronates
Further Information
Received
8 July 2010
Publication Date:
30 August 2010 (online)
Publication History
Publication Date:
30 August 2010 (online)
![](https://www.thieme-connect.de/media/synthesis/201021/lookinside/thumbnails/10.1055-s-0030-1258237-1.jpg)
Abstract
Palladium-catalyzed Suzuki-type couplings of 3-pyridyl triflates with alkenylpinacol boronates proceed in good to excellent yields. Optimized conditions use Pd(PPh3)4 (10 mol%) as catalyst with K3PO4 (3 equiv) as base in 1,4-dioxane.
Key words
boron - cross-coupling - heterocycles - palladium - pyridines
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- Supporting Information
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