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Synthesis 2011(2): 303-315
DOI: 10.1055/s-0030-1258352
DOI: 10.1055/s-0030-1258352
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis and Characterization of Donor-Functionalized N,S-Compounds Containing the ortho-Aminothiophenol Motif
Further Information
Received
5 October 2010
Publication Date:
03 December 2010 (online)
Publication History
Publication Date:
03 December 2010 (online)
Abstract
A series of twenty S-benzyl ortho-aminothiophenol and S,S′-xylylene-bridged bis(ortho-aminothiophenol) compounds and their imine derivatives have been synthesized in moderate to excellent yields and characterized. The syntheses were optimized, including large-scale syntheses, and an improved purification method involving the HCl salt was developed. This paper also serves as a comprehensive review of xylylene-bridged bis(ortho-aminothiophenol) compounds.
Key words
Schiff bases - sulfur - nitrogen - ligands - alkylation
- Supporting Information for this article is available online:
- Supporting Information
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