Abstract
Rasta resin-DMAP, a new heterogeneous polystyrene-based amine,
has been synthesized and used as a catalyst in addition reactions
of carbon dioxide to epoxides to afford cyclic carbonate products.
This new material was found to be a more efficient catalyst than
divinyl benzene cross-linked polystyrene-supported DMAP, and was
readily recovered and reused without significant loss of catalytic
activity.
Key words
polymer-supported organocatalyst - polystyrene - DMAP - carbon dioxide - cyclic carbonate
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General Procedure
for CO
2
Addition
Reactions
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