Synthesis 2012; 44(17): 2786-2792
DOI: 10.1055/s-0032-1316750
paper
© Georg Thieme Verlag Stuttgart · New York

Chemoselective Reactions of Secondary Phosphine Chalcogenides with Vinyloxyalkylamines: Synthesis of a Novel Family of Functional Phosphinoсhalcogenоic Amides

Nina K. Gusarova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   Email: boris_trofimov@irioch.irk.ru
,
Pavel A. Volkov
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   Email: boris_trofimov@irioch.irk.ru
,
Nina I. Ivanova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   Email: boris_trofimov@irioch.irk.ru
,
Ludmila A. Oparina
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   Email: boris_trofimov@irioch.irk.ru
,
Nikita A. Kolyvanov
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   Email: boris_trofimov@irioch.irk.ru
,
Oksana V. Vysotskaya
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   Email: boris_trofimov@irioch.irk.ru
,
Ludmila I. Larina
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   Email: boris_trofimov@irioch.irk.ru
,
Boris A. Trofimov*
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   Email: boris_trofimov@irioch.irk.ru
› Author Affiliations
Further Information

Publication History

Received: 17 May 2012

Accepted after revision: 23 June 2012

Publication Date:
08 August 2012 (online)


Abstract

The reactions of secondary phosphine сhalcogenides with vinyloxyalkylamines proceed chemoselectively in triethylamine–carbon tetrachloride under mild conditions to give the corresponding phosphinoсhalcogenоic amides bearing vinyloxy moieties in 78–95% yields.