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Synthesis 2014; 46(02): 165-169
DOI: 10.1055/s-0033-1338551
DOI: 10.1055/s-0033-1338551
practical synthetic procedures
Silver Acetate Mediated Acetoxylations of Alkyl Halides
Further Information
Publication History
Received: 20 September 2013
Accepted after revision: 25 September 2013
Publication Date:
04 November 2013 (online)
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Abstract
Silver acetate promotes the acetoxylation of alkyl halides under neutral reaction conditions. The reaction is applicable to primary and activated secondary alkyl halides, and 2,2-dibromoacetophenones for preparing the corresponding acetates in good yields. The presence of ester, amide, nitrile, hydroxy, and OTBDMS functions on the substrate is tolerated.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information