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Synthesis 2014; 46(07): 887-892
DOI: 10.1055/s-0033-1340681
DOI: 10.1055/s-0033-1340681
paper
An Efficient Synthetic Approach to Substituted Trisphenols (Phloroglucide Analogues) Using Tungstosilicic Acid in Water
Further Information
Publication History
Received: 17 November 2013
Accepted after revision: 08 January 2014
Publication Date:
11 February 2014 (online)
Abstract
Tungstosilicic acid was found to be an efficient catalyst for the synthesis of trisphenols using the reaction of 2,6-bis(hydroxymethyl)phenols with phenols in an aqueous medium. The catalytic reactivity of tungstosilicic acid in boiling water was examined with a series of substrates, demonstrating that this catalyst is reactive in the presence of a variety of functionalities.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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