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Synlett 2014; 25(12): 1731-1734
DOI: 10.1055/s-0033-1341272
DOI: 10.1055/s-0033-1341272
letter
Silver-Mediated Radical Trifluoromethylarylation of Activated Alkenes for the Synthesis of Oxindoles Bearing a CF3 Group
Further Information
Publication History
Received: 21 March 2014
Accepted after revision: 28 March 2014
Publication Date:
12 May 2014 (online)
Abstract
A radical trifluoromethylarylation of N-arylacrylamides with in situ generated [AgCF3] species from Me3SiCF3 and AgF in DMF is established through a tandem radical addition and C–H activation pathway. It provided a concise method to prepare 21 examples of CF3-containing oxindoles within four hours.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000083.
- Supporting Information
-
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During this manuscript was in preparation, other two examples of trifluoromethylarylation of N-arylacrylamides appeared: