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Synthesis 2015; 47(18): 2860-2868
DOI: 10.1055/s-0034-1378739
DOI: 10.1055/s-0034-1378739
paper
Studies toward the Total Synthesis of Tianchimycins A and B: Construction of the Complete C1–C16 Framework
Further Information
Publication History
Received: 12 March 2015
Accepted after revision: 28 April 2015
Publication Date:
25 June 2015 (online)
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Abstract
A stereoselective synthesis of the complete C1–C16 framework of tianchimycins A and B is described. Key transformations include Horner–Wadsworth–Emmons, Evans aldol, Gilman’s and stereoselective alkylation reactions.
Key words
Horner–Wadsworth–Emmons - Evans aldol - Gilman’s reaction - stereoselective alkylation - tianchimycinsSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380281.
- Supporting Information
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