Rediscovering the Chemistry of Sulfur Dioxide: New Developments in Synthesis and Catalysis

Alex S. Deeming; Edward J. Emmett; Charlotte S. Richards-Taylor; Michael C. Willis

doi:10.1055/s-0034-1379042

Synthesis, Table of Contents

Synthesis 2014; 46(20): 2701-2710
DOI: 10.1055/s-0034-1379042

short review

Rediscovering the Chemistry of Sulfur Dioxide: New Developments in Synthesis and Catalysis

Alex S. Deeming

Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK Fax: +44(1865)285002 Email: michael.willis@chem.ox.ac.uk

,

Edward J. Emmett

Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK Fax: +44(1865)285002 Email: michael.willis@chem.ox.ac.uk

,

Charlotte S. Richards-Taylor

Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK Fax: +44(1865)285002 Email: michael.willis@chem.ox.ac.uk

,

Michael C. Willis*

Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK Fax: +44(1865)285002 Email: michael.willis@chem.ox.ac.uk

› Author Affiliations

Abstract

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Abstract

The recent development of several sulfur dioxide surrogates has seen a renaissance in its chemistry, with a number of new synthetic methods being reported. This article reviews the reactions of sulfur dioxide and sulfur dioxide surrogates, with an emphasis on recent examples.

1 Introduction

2 Sulfur Dioxide Surrogates

3 Reactions with Organometallic Reagents

4 Pericyclic Reactions

5 Sulfur Dioxide Radical Chemistry

6 Transition-Metal-Catalysed Processes

7 Conclusions

Key words

sulfur dioxide - surrogate - sulfinate - metal catalysis - sulfone - sulfonamide

Full Text

References

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