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Synthesis 2015; 47(06): 737-759
DOI: 10.1055/s-0034-1379720
DOI: 10.1055/s-0034-1379720
review
Carbon–Hydrogen Bond Functionalizations Mediated by Copper
Further Information
Publication History
Received: 15 August 2014
Accepted after revision: 17 September 2014
Publication Date:
17 February 2015 (online)
Abstract
Direct carbon–hydrogen bond functionalization has attracted considerable attention and plays a key role in organic transformations. Currently, copper is showing great potential as a catalyst in C–H bond-functionalization reactions because of its low cost and unique reactivity. This review summarizes the recent advances in copper-catalyzed C–H bond functionalizations from carbon–carbon and carbon–heteroatom (O, N and S) bond-forming reactions through activation of C–H bonds.
1 Introduction
2 Carbon–Carbon Bond Formation
2.1 Csp–H Bond Functionalization
2.2 Csp2–H Bond Functionalization
2.3 Csp3–H Bond Functionalization
3 Carbon–Heteroatom Bond Formation
3.1 Carbon–Oxygen Bond Formation
3.2 Carbon–Nitrogen Bond Formation
3.3 Carbon–Sulfur Bond Formation
4 Conclusion
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