Reagent and Catalyst Design for Asymmetric Hypervalent Iodine Oxidations

Florian Berthiol

doi:10.1055/s-0034-1379892

Synthesis, Inhaltsverzeichnis

Synthesis 2015; 47(05): 587-603
DOI: 10.1055/s-0034-1379892

review

Reagent and Catalyst Design for Asymmetric Hypervalent Iodine Oxidations

Florian Berthiol*

Département de Chimie Moléculaire (SERCO), UMR-5250, ICMG FR-2607, Université Joseph Fourier, 301 Rue de la Chimie, BP 53, 38041 Grenoble Cedex 9, France eMail: Florian.Berthiol@ujf-grenoble.fr

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Abstract

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Abstract

In this review are compiled the different possible transformations using environmentally benign chiral hypervalent iodine reagents and catalysts. Herein is presented an overview of asymmetric oxidation of sulfides to sulfoxides, oxidation of alkenes, α-functionalization of carbonyl compounds and dearomatization reactions.

1 Introduction

2 Chiral Hypervalent Iodine Reagents

3 Oxidation of Sulfides to Sulfoxides

4 Oxidation of Alkenes

5 α-Functionalization of Carbonyl Compounds

6 Dearomatization Reactions

7 Conclusion

Key words

hypervalent iodine - asymmetric transformations - homogeneous organocatalysis - oxidations - carbon–carbon bond formations - carbon–heteroatom bond formations

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Referenzen

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