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DOI: 10.1055/s-0032-1318330
Iodine in Modern Oxidation Catalysis
Publikationsverlauf
Received: 21. Januar 2013
Accepted after revision: 07. Februar 2013
Publikationsdatum:
21. März 2013 (online)


Abstract
This review discusses the origins of iodine-mediated oxidation catalysis and gives a comprehensive overview on this young field of research. The focus is set on oxidative C–X bond-forming reactions starting from two unfunctionalized C–H and X–H bonds. In addition, iodine-mediated oxidative domino reactions will be discussed.
1 Introduction
2 Why Iodine?
3 C–N Bond Formations
3.1 Aziridinations
3.2 Oxidative Aminations of Heteroarenes
3.3 Oxidative Aminations of sp3 C–H Bonds
3.4 Oxidative Amidations and Esterifications
4 C–O and C–S Bond Formations
5 C–C Bond Formations
6 Simple Oxidations of Functional Groups
7 Oxidative Domino Reactions
8 Conclusion