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Synthesis 2015; 47(17): 2529-2537
DOI: 10.1055/s-0034-1380522
DOI: 10.1055/s-0034-1380522
special topic
Reactions of Sulfonium Salts with 2,3-Dioxopyrrolidine Derivatives: A Concise Synthesis of Spirocyclopropane
Further Information
Publication History
Received: 07 February 2015
Accepted after revision: 11 March 2015
Publication Date:
19 May 2015 (online)
Abstract
An efficient base-promoted spirocyclopropanation of 2,3-dioxopyrrolidine derivatives with sulfonium salts is described. This reaction enables a novel concise access to polysubstituted spirocyclopropane derivatives in good yields and with a trans/cis ratio of up to >20:1 under mild conditions.
Key words
spiro compounds - spirocyclopropane - sulfur ylides - sulfonium salt - 2,3-dioxopyrrolidine - heterocyclesSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380522.
- Supporting Information
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