New Reaction of Fullerene C₆₀ with Cyanoacrylates and Ethylmagnesium Bromide in the Presence of Titanium(IV) Isopropoxide

Abstract

The reaction of fullerene C₆₀ with cyanoacrylates and ethylmagnesium bromide in the presence of stoichiometric amounts of titanium(IV) isopropoxide was studied for the first time. Under the developed conditions, cyanoacrylates, unlike carboxylic acid esters and nitriles, were found to react with C₆₀ to form aminofullerocyclopropanes, which are otherwise difficult to access.

Key words

[60]fullerene - cyanoacrylates - organomagnesium compounds - aminocyclopropanation

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