Synthesis, Inhaltsverzeichnis Synthesis 2016; 48(01): 136-140DOI: 10.1055/s-0035-1560498 paper © Georg Thieme Verlag Stuttgart · New York New Reaction of Fullerene C60 with Cyanoacrylates and Ethylmagnesium Bromide in the Presence of Titanium(IV) Isopropoxide Airat R. Tuktarov* Institute of Petrochemistry and Catalysis, Russian Academy of Science, pr. Oktyabrya 141, 450075, Ufa, Russian Federation eMail: tuktarovar@gmail.com , Zulfiya R. Shakirova Institute of Petrochemistry and Catalysis, Russian Academy of Science, pr. Oktyabrya 141, 450075, Ufa, Russian Federation eMail: tuktarovar@gmail.com , Artur R. Khuzin Institute of Petrochemistry and Catalysis, Russian Academy of Science, pr. Oktyabrya 141, 450075, Ufa, Russian Federation eMail: tuktarovar@gmail.com , Usein M. Dzhemilev Institute of Petrochemistry and Catalysis, Russian Academy of Science, pr. Oktyabrya 141, 450075, Ufa, Russian Federation eMail: tuktarovar@gmail.com › Institutsangaben Artikel empfehlen Abstract Artikel einzeln kaufen Alle Artikel dieser Rubrik Abstract The reaction of fullerene C60 with cyanoacrylates and ethylmagnesium bromide in the presence of stoichiometric amounts of titanium(IV) isopropoxide was studied for the first time. Under the developed conditions, cyanoacrylates, unlike carboxylic acid esters and nitriles, were found to react with C60 to form aminofullerocyclopropanes, which are otherwise difficult to access. Key words Key words[60]fullerene - cyanoacrylates - organomagnesium compounds - aminocyclopropanation Volltext Referenzen References 1a Friedman SH, Ganapathi PS, Rubin Y, Kenyon GL. J. Med. Chem. 1998; 41: 2424 1b Brettreich M, Hirsch A. Tetrahedron Lett. 1998; 39: 2731 1c Mashino T, Shimotohno K, Ikegami N, Nishikawa D, Okuda K, Takahashi K, Nakamura S, Mochizuki M. Bioorg. Med. Chem. 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