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Synthesis 2017; 49(01): 1-16
DOI: 10.1055/s-0035-1561625
DOI: 10.1055/s-0035-1561625
short review
Secondary Alkyl Groups in Palladium-Catalyzed Cross-Coupling Reactions
Further Information
Publication History
Received: 28 March 2016
Accepted: 02 April 2016
Publication Date:
27 April 2016 (online)
This review is dedicated to Professor Dieter Enders on the occasion of his 70th birthday.
Abstract
Important classes of cross-coupling reactions are those leading to the incorporation of secondary alkyl groups. While early work in cross-coupling focused mainly on primary alkyl groups, the past decade has seen significant advances in introducing secondary and tertiary groups. This review will focus on the advances made in recent years referencing landmark publications where necessary. Expansion of scope, ease of reaction setup, and mechanistic considerations will be stressed. Applications of methodologies towards complex scaffolds and natural products will be also be evaluated.
1 Introduction
2.1 Suzuki Coupling
2.2 Mizoroki–Heck Coupling
2.3 Stille Coupling
2.4 Sonagashira Coupling
2.5 Kumada Coupling
2.6 Negishi Coupling
2.7 Hiyama Coupling
2.8 Lithium Coupling
2.9 Titanium Coupling
2.10 C–H Activation
3 Conclusion
-
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For recent reviews see: