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Synthesis 2016; 48(17): 2732-2738
DOI: 10.1055/s-0035-1561664
DOI: 10.1055/s-0035-1561664
short review
Sonogashira-Like Coupling Reactions with Phosphine–Gold(I) Alkynyl Complexes
Further Information
Publication History
Received: 26 April 2016
Accepted: 29 April 2016
Publication Date:
16 June 2016 (online)
Abstract
Phosphine–gold(I) alkynyl complexes are stable compounds that can be subjected to palladium-catalyzed cross-coupling reactions. This article outlines the synthesis of such compounds and their ability to play the role as substrates in Sonogashira couplings is covered. This synthetic approach is particularly attractive when the related terminal alkynes are unstable.
1 Introduction
2 Phosphine–Gold(I) Alkynyl Complexes
3 Sonogashira-Like Couplings
4 Transmetalation Step – Mechanistic Insight
5 Acetylenic Scaffolding with Tetraethynylethene Derivatives
6 Conclusion
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For recent reviews on the synthesis of oligoynes, see:
For extended TTFs with a radiaannulene unit as spacer group, see: