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Synthesis 2016; 48(21): 3696-3700
DOI: 10.1055/s-0035-1562783
DOI: 10.1055/s-0035-1562783
psp
An Efficient and Practical Method for Olefin Dihydroxylation
Further Information
Publication History
Received: 21 April 2016
Accepted after revision: 16 June 2016
Publication Date:
16 August 2016 (online)
Abstract
An efficient and economic procedure was developed for the dihydroxylation of various olefin derivatives with commercial KMnO4 as the oxidant in the presence of a quaternary ammonium salt. This practical procedure is suitable for large-scale production of cis-dihydroxy compounds, even those bearing primary and secondary alcohol groups, without overoxidation.
Keyword
dihydroxylation - diols - acrylates - alkenes - potassium permanganate - quaternary ammonium saltsSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1562783.
- Supporting Information
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