Recent Advances in Transition-Metal-Free Aryl C–B Bond Formation

Kai Chen; Linghua Wang; Ge Meng; Pengfei Li

doi:10.1055/s-0036-1590913

Synthesis, Inhaltsverzeichnis

Synthesis 2017; 49(21): 4719-4730
DOI: 10.1055/s-0036-1590913

review

Recent Advances in Transition-Metal-Free Aryl C–B Bond Formation

Kai Chen

^aSchool of Pharmacy, Health Science Center, Xi’an Jiaotong University, Xi’an 710061, P. R. of China eMail: mengge@mail.xjtu.edu.cn

,

Linghua Wang

^bFrontier Institute of Science and Technology and Frontier Institute of Chemistry, Xi’an Jiaotong University, Xi’an 710054, P. R. of China eMail: lipengfei@mail.xjtu.edu.cn

,

Ge Meng*

^aSchool of Pharmacy, Health Science Center, Xi’an Jiaotong University, Xi’an 710061, P. R. of China eMail: mengge@mail.xjtu.edu.cn

,

Pengfei Li *

^bFrontier Institute of Science and Technology and Frontier Institute of Chemistry, Xi’an Jiaotong University, Xi’an 710054, P. R. of China eMail: lipengfei@mail.xjtu.edu.cn

› Institutsangaben

Abstract

Alle Artikel dieser Rubrik

Published as part of the Special Topic Modern Strategies for Borylation in Synthesis

Abstract

Arylboronic acids and their derivatives are widely used in organic synthesis. Conventional methods for their preparation require either reactive organometallic reagents or transition-metal-mediated processes. In recent years, transition-metal-free reactions for aryl C–B bond formation that obviate preformed organometallic reagents have gained interest and have developed rapidly. These new reactions have shown significant advantages for the preparation of functionalized molecules. In this review, an overview of the recent advances in transition-metal-free aromatic borylation reactions is provided.

1 Introduction

2 Transition-Metal-Free Transformations of C_Ar–N Bonds to C_Ar–B Bonds

3 Transition-Metal-Free Transformations of C_Ar–X Bonds to C_Ar–B Bonds

4 Transition-Metal-Free Transformations of C_Ar–H Bonds to C_Ar–B Bonds

5 Conclusion

Key words

arenes - cross-coupling - boron - radical reaction - photochemistry

Volltext

Referenzen

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