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Synthesis 2018; 50(17): 3395-3401
DOI: 10.1055/s-0037-1610138
DOI: 10.1055/s-0037-1610138
special topic
Photoorganocatalytic Atom Transfer Radical Addition of Bromoacetonitrile to Aliphatic Olefins
Further Information
Publication History
Received: 25 February 2018
Accepted after revision: 09 April 2018
Publication Date:
29 May 2018 (online)
![](https://www.thieme-connect.de/media/synthesis/201817/lookinside/thumbnails/ss-2018-c0112-st_10-1055_s-0037-1610138-1.jpg)
Published as part of the Special Topic Photoredox Methods and their Strategic Applications in Synthesis
Abstract
A green and cheap protocol for the photocatalytic atom transfer radical addition (ATRA) of bromoacetonitrile to aliphatic alkenes is presented. The use of benzoin methyl ehter as the photocatalyst and irradiation using a household lightbulb leads to a highly useful synthetic method for the conversion of a wide range of substituted aliphatic olefins into the corresponding bromonitriles.
Key words
photoorganocatalysis - photochemistry - ATRA reaction - alkenes - bromoacetonitrile - nitrilesSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1610138.
- Supporting Information
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