Organoiodine-Catalyzed Enantioselective Intramolecular Oxy­aminations of Alkenes with N-(Fluorosulfonyl)carbamate

Abstract

Organoiodine-catalyzed enantioselective intramolecular oxyaminations were realized by the use of benzyl N-(fluorosulfonyl)carbamate as the exogenous nitrogen source. The method allows access to enantioenriched lactones and oxazolines, starting from γ,δ- and δ,ε-unsaturated esters and N-allyl amides, respectively.

Key words

iodine - asymmetric catalysis - oxyamination - lactones - oxazoline

• References

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