Chromium-Catalyzed Cross-Couplings and Related Reactions

Jie Li; Paul Knochel

doi:10.1055/s-0037-1611756

Synthesis, Table of Contents

Synthesis 2019; 51(10): 2100-2106
DOI: 10.1055/s-0037-1611756

short review

Chromium-Catalyzed Cross-Couplings and Related Reactions

Jie Li*

Ludwig-Maximilians-Universität München, Department Chemie und Biochemie, Butenandtstr. 5–13, Haus F, 81377 Munich, Germany Email: jjackli@jiangnan.edu.cn Email: paul.knochel@cup.uni-muenchen.de

,

Paul Knochel *

Ludwig-Maximilians-Universität München, Department Chemie und Biochemie, Butenandtstr. 5–13, Haus F, 81377 Munich, Germany Email: jjackli@jiangnan.edu.cn Email: paul.knochel@cup.uni-muenchen.de

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Abstract

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Abstract

Transition-metal-catalyzed cross-couplings have been recognized as a powerful tool for sustainable syntheses. Despite the fact that remarkable progress was achieved by palladium and nickel catalysis, the high price and toxicity still remained a drawback. Recently, naturally more abundant and less toxic low-valent chromium salts, such as Cr(II) and Cr(III) chlorides, displayed notable unique catalytic reactivity. Thus, recent progress in the field of chromium-catalyzed cross-couplings and related reactions are highlighted in the present short review until December 2018.

1 Introduction and Early Chromium-Mediated Reactions

2 Chromium-Catalyzed Cross-Couplings and Related Reactions

3 Conclusion

Key words

chromium - cross-coupling - C–H activation - C–X formation - homogeneous catalysis

Full Text

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