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Synlett 2019; 30(14): 1703-1707
DOI: 10.1055/s-0037-1612088
DOI: 10.1055/s-0037-1612088
cluster
Organoselenium-Catalyzed Polymerization of Aniline with Hydrogen Peroxide as Oxidant
This work was financially supported by the Nature Science Foundation of Jiangsu Province (BK20181449), the National Natural Science Foundation of China (21673202), the Jiangsu Provincial Six Talent Peaks Project (XCL-090), and the Priority Academic Program Development of Jiangsu Higher Education Institutions.Weitere Informationen
Publikationsverlauf
Received: 27. November 2018
Accepted after revision: 26. Dezember 2018
Publikationsdatum:
05. Februar 2019 (online)
Published as part of the Cluster Organosulfur and Organoselenium Compounds in Catalysis
Abstract
A convenient method for the synthesis of polyanilines was developed through the organoselenium-catalyzed oxidation of anilines with H2O2. Unlike reported methods, this reaction generates no wastes other than water. These green features make the method much more practical in terms of large-scale preparation. Moreover, it is the first example of an application of organoselenium catalysis techniques in aniline polymerization reactions and might be an important advance in the fields of both organoselenium catalysis and polyanilines.
Key words
selenium catalysis - organoselenium compounds - green chemistry - aniline - polymerization - polyanilineSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1612088.
- Supporting Information
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For selected articles, please see:
For reviews, please see:
For selected articles, see:
For selected articles on organoselenium-catalyzed green reactions, see:
For our works on Se catalysis, see:
For reviews, see:
For previous works on oxidative polymerization of aniline with H2O2, see: