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Synthesis 2020; 52(06): 893-900
DOI: 10.1055/s-0039-1690765
DOI: 10.1055/s-0039-1690765
paper
Palladium-Catalyzed/Copper-Mediated Desulfurization and Arylation of Quinoline-2-(1H)-thione for Rapid Access to Quinoline Derivatives
We are thankful for the financial support from the National Nature Science Foundation of China (No. 21562036), and the Key Talent Projects in Gansu Province (2018A-004).Further Information
Publication History
Received: 21 September 2019
Accepted after revision: 26 November 2019
Publication Date:
09 December 2019 (online)
Abstract
An efficient method for carbon–carbon bond formation is described. The process employs the palladium-catalyzed and copper-mediated cross-coupling of quinoline-2-(1H)-thiones with arylboronic acids or alkynes through C–S bond cleavage without an inert atmosphere. The method provides rapid and general access to a diverse range of 2-substituted quinolines in a single step from a wide range of quinoline-2-(1H)-thiones and arylboronic acids or alkynes.
Keywords
C–S bond cleavage - arylboronic acids - alkynes - quinoline-2-thiones - Liebeskind–Srogl cross couplingSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690765.
- Supporting Information
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