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Synthesis 2020; 52(22): 3295-3325
DOI: 10.1055/s-0040-1707884
DOI: 10.1055/s-0040-1707884
review
Synthetic Advances in the C–H Activation of Rigid Scaffold Molecules
This work was supported by a grant from Science Foundation Ireland (SFI IvP 13/IA/1894).Weitere Informationen
Publikationsverlauf
Received: 02. April 2020
Accepted after revision: 12. Mai 2020
Publikationsdatum:
03. Juli 2020 (online)
Dedicated to Prof. Dr. Henning Hopf
Abstract
The remarkable structural and electronic properties of rigid non-conjugated hydrocarbons afford attractive opportunities to design molecular building blocks for both medicinal and material applications. The bridgehead positions provide the possibility to append diverse functional groups at specific angles and in specific orientations. The current review summarizes the synthetic development in CH functionalization of three rigid scaffolds namely: (a) cubane, (b) bicyclo[1.1.1]pentane (BCP), (c) adamantane.
1 Introduction
2 Cubane
2.1 Cubane Synthesis
2.2 Cubane Functionalization
3 Bicyclo[1.1.1]pentane (BCP)
3.1 BCP Synthesis
3.2 BCP Functionalization
4 Adamantane
4.1 Adamantane Synthesis
4.2 Adamantane Functionalization
5 Conclusions and Outlook
-
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