Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions

Zhi-Yong Zeng; Xiaoli Zhao; Junhai Huang; Jing Zhu; Tongxia Jin; Lianrui Hu; Wei-Tao Dou; Lin Xu

doi:10.1055/s-0042-1751486

Synlett, Inhaltsverzeichnis

Synlett 2024; 35(01): 130-134
DOI: 10.1055/s-0042-1751486

cluster

Functional Dyes

Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions

Zhi-Yong Zeng

^aSchool of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P. R. of China

,

Xiaoli Zhao

^aSchool of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P. R. of China

,

Junhai Huang∗

^bCollege of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, P. R. of China

^cState Key Laboratory of New Drug and Pharmaceutical Process, Shanghai Institute of Pharmaceutical Industry, China State Institute of Pharmaceutical Industry, Shanghai 201203, P. R. of China

,

Jing Zhu

^dDepartment of Philosophy, East China Normal University, 500 Dongchuan Road, Shanghai 200241, P. R. of China

,

Tongxia Jin

^aSchool of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P. R. of China

,

Lianrui Hu∗

^aSchool of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P. R. of China

,

Wei-Tao Dou

^aSchool of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P. R. of China

,

Lin Xu∗

^aSchool of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P. R. of China

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Abstract

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Abstract

Functionalized metallacages have attracted tremendous attention in recent years due to their potential applications in optical sensing, catalysis, and recognition. A novel anthracene-functionalized metallacage was synthesized and characterized in detail by UV/vis spectroscopy, 1D/2D NMR, electrospray ionization time-of-flight mass spectrometry, and X-ray single crystal diffraction. This metallacage exhibited a specific fluorescence enhancement response to OH^–, PO₄ ^3–, and AcO^– anions, and further analysis indicated that this was due to anion-induced metallacage disassembly.

Key words

supramolecular chemistry - self-assembly - metallacages - fluorescence - anion recognition

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Referenzen

References and Notes
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