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Synlett 2024; 35(01): 130-134
DOI: 10.1055/s-0042-1751486
DOI: 10.1055/s-0042-1751486
cluster
Functional Dyes
Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions
This work was supported by the National Nature Science Foundation of China (No. 22103062), Shanghai Pujiang Program (No. 22PJ1402800), the Fundamental Research Funds for the Central Universities (2022QKT003), and the Open Research Fund of Shanghai Key Laboratory of Green Chemistry and Chemical Processes.
Abstract
Functionalized metallacages have attracted tremendous attention in recent years due to their potential applications in optical sensing, catalysis, and recognition. A novel anthracene-functionalized metallacage was synthesized and characterized in detail by UV/vis spectroscopy, 1D/2D NMR, electrospray ionization time-of-flight mass spectrometry, and X-ray single crystal diffraction. This metallacage exhibited a specific fluorescence enhancement response to OH–, PO4 3–, and AcO– anions, and further analysis indicated that this was due to anion-induced metallacage disassembly.
Key words
supramolecular chemistry - self-assembly - metallacages - fluorescence - anion recognitionSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0042-1751486.
- Supporting Information
Publication History
Received: 09 May 2023
Accepted after revision: 24 July 2023
Article published online:
07 September 2023
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