Solvent-Free Oxidations of Alcohols, Oximes, Aldehydes and Cyclic Acetals by Pyridinium Chlorochromate

Peyman Salehi; Habib Firouzabadi; Afsaneh Farrokhi; Mostafa Gholizadeh

doi:10.1055/s-2001-18443

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Synthesis 2001(15): 2273-2276
DOI: 10.1055/s-2001-18443

PAPER

Solvent-Free Oxidations of Alcohols, Oximes, Aldehydes and Cyclic Acetals by Pyridinium Chlorochromate

Peyman Salehi*^a, Habib Firouzabadi^b, Afsaneh Farrokhi^c, Mostafa Gholizadeh^d
^a Department of Phytochemistry, Medicinal Plants Research Institute, Shahid Beheshti University, Evin, Tehran, Iran
Fax: +98(21)2418679; e-Mail: p-salehi@cc.sbu.ac.ir ;
^b Department of Chemistry, Shiraz University, Shiraz 71454, Iran
^c Department of Chemistry, Razi University, Kermanshah, Iran
^d Department of Chemistry, Sabzevar Teacher Training University, Sabzevar, Iran

Further Information

Publication History

Received 17 January 2001
Publication Date:
05 August 2004 (online)

Abstract
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Abstract

Oxidative transformations of alcohols, oximes and cyclic acetals to carbonyl compounds proceed efficiently by pyridinium chlorochromate (PCC) under solvent-free conditions. The oxidation of aromatic and cinnamylic aldehydes to carboxylic acids, which does not occur by PCC in solution, is achieved satisfactorily in the absence of solvent.

Key words

oxidations - alcohols - aldehydes - acetals - pyridinium chlorochromate

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